ELECTROSYNTHESIS AND STUDIES OF ADDUCTS OF 2-AMINO-1-METHYLBENZIMIDAZOLE WITH METAL-CHELATES BASED ON 2-TOSYLAMINO-N-SALICYLIDENEANILINE

Authors
GARNOVSKII DA SOUSA A ANTSYSHKINA AS SADIKOV GG VASILCHENKO IS SIGEIKIN SG BURLOV AS CASTINEIRAS A GARNOVSKII AD
Citation
Da. Garnovskii et al., ELECTROSYNTHESIS AND STUDIES OF ADDUCTS OF 2-AMINO-1-METHYLBENZIMIDAZOLE WITH METAL-CHELATES BASED ON 2-TOSYLAMINO-N-SALICYLIDENEANILINE, Russian chemical bulletin, 45(8), 1996, pp. 1988-1992
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
8
Year of publication
1996
Pages
1988 - 1992
Database
ISI
SICI code
1066-5285(1996)45:8<1988:EASOAO>2.0.ZU;2-E
Abstract
For the first time the adducts of 2-amino-1-methylbenzimidazole (L) wi th cobalt, copper, and zinc chelates based on 2-tosylamino-N-salicylid eneaniline were electrochemically synthesized, and the properties and structures of these adducts were studied. According to the IR and H-1 NMR spectral data on the adducts obtained and X-ray structural analysi s of the copper complex, the adducts of composition mL . ML' . nH(2)O (m = 1 or 2; n = 0, 1, or 2) contain the L moiety bonded to the metal atom through the pyridine-type N atom of the imidazole ring.