AROMATIZATIONAL RHODIATION OF DENE-4-METHYL-4-TRICHLOROMETHYLCYCLOHEXA-2,5-DIENE UNDER THE ACTION OF (PH(3)P)(3)RH(CO)H AND (C2H4)(2)RH(ACAC) AS A NOVEL ROUTE TO P-TOLYLCYCLOPENTADIENYL COMPLEXES OF TRANSITION-METALS

Authors
NIKANOROV VA MOCHALOVSKII SE KOMISSAROV AV SERGEEV SV ZVEREV DV STRELKOVA TI VORONTSOV EV
Citation
Va. Nikanorov et al., AROMATIZATIONAL RHODIATION OF DENE-4-METHYL-4-TRICHLOROMETHYLCYCLOHEXA-2,5-DIENE UNDER THE ACTION OF (PH(3)P)(3)RH(CO)H AND (C2H4)(2)RH(ACAC) AS A NOVEL ROUTE TO P-TOLYLCYCLOPENTADIENYL COMPLEXES OF TRANSITION-METALS, Russian chemical bulletin, 45(8), 1996, pp. 1993-1995
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
8
Year of publication
1996
Pages
1993 - 1995
Database
ISI
SICI code
1066-5285(1996)45:8<1993:AROD>2.0.ZU;2-E
Abstract
Condensation of 4-methyl-4-trichloromethylcyclohexa-2,5-dienone with c yclopentadiene gave the first representative of cross-conjugated penta fulvenes of the paro-semiquinoid series: ene-4-methyl-4-trichloromethy lcyclohexa-2,5-diene. This fulvene undergoes a novel redox aromatizati onal skeletal rearrangement under the action of (Ph(3)P)(3)Rh(CO)H and (C2H4)(2)Rh(acac) to give e[eta(5)-(p-tolylcyclopentadienyl)]dichloro rhodium and -p-tolylcyclopentadienyl)(mu-chloro)chlorohodium], respect ively.