THE SYNTHESIS OF TRICARBONYL(2,4-CYCLOHEPTADIENE-1,6-DIONE)IRON AND TRICARBONYL(2,4-CYCLOOCTADIENE-1,6-DIONE)IRON

Authors
MORITA N ITO S ASAO T
Citation
N. Morita et al., THE SYNTHESIS OF TRICARBONYL(2,4-CYCLOHEPTADIENE-1,6-DIONE)IRON AND TRICARBONYL(2,4-CYCLOOCTADIENE-1,6-DIONE)IRON, Journal of organometallic chemistry, 460(1), 1993, pp. 67-72
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
460
Issue
1
Year of publication
1993
Pages
67 - 72
Database
ISI
SICI code
0022-328X(1993)460:1<67:TSOTAT>2.0.ZU;2-G
Abstract
ricarbonyl(6-hydroxy-2,4-cycloheptadien-1-one)iron derived from tricar bonyl(tropone)iron was easily oxidized to give tricarbonyl(2,4-cyclohe ptadiene-1,6-dione)iron. This procedure was also extended to tricarbon yl(2-substituted tropone)iron and (bicyclo[5.1.0]octa-3,5-dien-2-one)t ricarbonyliron to yield tricarbonyl(2-substituted 2,4-cycloheptadiene- 1,6-dione)iron and tricarbonyl(2,4-cyclooctadiene-1,6-dione)iron, resp ectively.