DEPROTONATION OF DECAMETHYLFERROCENIUM CATION - NEW APPROACH TO ALKYLGROUP FUNCTIONALIZATION IN TRANSITION-METAL COMPLEXES

Authors
NOVIKOVA LN ZAGOREVSKII DV USTYNYUK NA
Citation
Ln. Novikova et al., DEPROTONATION OF DECAMETHYLFERROCENIUM CATION - NEW APPROACH TO ALKYLGROUP FUNCTIONALIZATION IN TRANSITION-METAL COMPLEXES, Journal of organometallic chemistry, 460(1), 1993, pp. 30000006-30000007
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
460
Issue
1
Year of publication
1993
Pages
30000006 - 30000007
Database
ISI
SICI code
0022-328X(1993)460:1<30000006:DODC-N>2.0.ZU;2-Y
Abstract
Deprotonation of decamethylferrocenium tetrafluorborate (20-degrees-C, THF, (t)BuOK or iPr2NH, Et3N) proceeds via intermediate formation of nonamethylferrocenylmethyl radical and results in the products of buto xylation and amination of methyl groups.