Electronic properties of both nanometer thickness (111) monocrystallin
e and nanocrystalline free standing silicon films were calculated with
in a self-consistent linear combination of atomic orbitals method. Gra
ined nature of the nanocrystalline films is found to induce both a dir
ect band gap and its reduction (down to about 2 eV) with respect to an
isolated grain of same size. (C) 1997 American Institute of physics.