GAS-PHASE HALO ALKYLATION OF C-60-FULLERENE BY ION-MOLECULE REACTION UNDER CHEMICAL-IONIZATION

Authors
SRINIVAS R VAIRAMANI M MATHEWS CK
Citation
R. Srinivas et al., GAS-PHASE HALO ALKYLATION OF C-60-FULLERENE BY ION-MOLECULE REACTION UNDER CHEMICAL-IONIZATION, Journal of the American Society for Mass Spectrometry, 4(11), 1993, pp. 894-897
Citations number
21
Categorie Soggetti
Chemistry Physical","Chemistry Analytical",Spectroscopy
Journal title
Journal of the American Society for Mass Spectrometry → ACNP
ISSN journal
10440305
Volume
4
Issue
11
Year of publication
1993
Pages
894 - 897
Database
ISI
SICI code
1044-0305(1993)4:11<894:GHAOCB>2.0.ZU;2-2
Abstract
Chemical ionization (CI) mass spectra of C60-fullerene were studied us ing 1,2-dibromoethane and 1,2-dichloroethane as CI reagents. The ion-m olecule reaction between C60 and C2H4X+ (X = Br and Cl) leads to the f ormation of (C60 + C2H4X)+ adducts. The collision-induced dissociation of the adducts reveal gas phase halo alkylation of C60-fullerene invo lving the C-C bond formation.