CRYSTAL-STRUCTURES OF CH2=CHCH2OC(O)CH2CH2SNCL3-CENTER-DOT-OPPH3 AND BUOC(O)CH(CH3)CH2SNCL3-CENTER-DOT-OPPH3

Authors
GIELEN M PAN HD TIEKINK ERT
Citation
M. Gielen et al., CRYSTAL-STRUCTURES OF CH2=CHCH2OC(O)CH2CH2SNCL3-CENTER-DOT-OPPH3 AND BUOC(O)CH(CH3)CH2SNCL3-CENTER-DOT-OPPH3, Bulletin des Societes chimiques belges, 102(7), 1993, pp. 447-453
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
102
Issue
7
Year of publication
1993
Pages
447 - 453
Database
ISI
SICI code
0037-9646(1993)102:7<447:COCAB>2.0.ZU;2-S
Abstract
The crystal structures of the title compounds, CH2=CHCH2OC(O)CH2CH2SnC l3.OPPh3 1 and BuOC(O)CH(CH3)CH2SnCl3.OPPh3 2, have been determined. T he Sn atom in each structure exists in a distorted octahedral geometry defined by three Cl atoms, the C and O atoms of a chelating alkoxycar bonylalkyl group and an O atom derived from the strongly attached OPPh 3 ligand.