K. Wang et Bde. Chatterton, MICROSPHERULES IN DEVONIAN SEDIMENTS - ORIGINS, GEOLOGICAL SIGNIFICANCE, AND CONTAMINATION PROBLEMS, Canadian journal of earth sciences, 30(8), 1993, pp. 1660-1667
We have studied various microspherules (<0.5 mm across) that were foun
d in Devonian sediments from Canada and China during our micropaleonto
logical studies (e.g., conodont picking). These spherules are similar
in appearance, but they are quite different in origin. A combined scan
ning electron microscope, energy dispersive X-ray, X-ray microdiffract
ion, and electron microprobe analysis enables us to determine their pr
obable origins: phosphatic conodont pearls of biological origin; silic
ate glass microtektites of terrestrial meteorite-impact origin; and bl
ack, magnetic iron spherules of probable extraterrestrial origin. We a
lso observed some contaminant spherules (glue spatters and steel slag)
of artificial origins. Studies of natural spherules in sediments can
provide important geological information that may be otherwise undetec
table.