The ultraluminous infrared Seyfert 1 galaxy Mrk 231 has been spectrall
y imaged in the K band with the new three-dimensional MPE integral hel
d spectrometer. The combined images of the H-2 emission lines show, fo
r the first time in an ultraluminous infrared galaxy, the presence of
an extended circumnuclear structure of hot molecular gas. The H-2 emit
ting region has a size of similar to 2.4 kpc and a hot molecular gas m
ass M(H2)(hot) similar to 2 x 10(4) M circle dot. The H-2 emission-lin
e ratios indicate that the gas is most likely thermally excited. If as
in NGC 7469 star formation is associated with the H-2 emission, the s
tarburst would have a far-IR luminosity L(FIR) similar to 1 x 10(12) L
circle dot. This value represents an upper limit, since a fraction of
the hot molecular gas may be excited by the radiation field emerging
from the nucleus. The K-band three-dimensional data cube also shows fo
r the first time the presence of extended narrow Pa alpha emission blu
eshifted by similar to 1400 km s(-1) with respect to the systemic velo
city, and located similar to 0.6 kpc northwest of the nucleus. The det
ection of CO absorption bands with a spatial distribution peaking on t
he K-band continuum provides evidence for a central stellar concentrat
ion. The low CO spectroscopic index indicates, however, dilution by ho
t dust emission or by a nonthermal active galactic nucleus. The Pa alp
ha/H alpha ratio confirms previous extinction measurements based on Ba
lmer line ratios, i.e., visual extinction of A(V) similar to 2.0-6.6 m
ag. The quasar-type nucleus of Mrk 231 should then be transparent at 2
mu m and also in hard X-rays. A weak nuclear He I lambda 2.058 mu m (
He I/Pa alpha = 0.032) is detected, and no detection of [Si VI] lambda
1.962 mu m is made, placing an upper limit of 4 x 10(-18) Wm(-2) for
the coronal gas emission. The ionizing source could either be a far-UV
and X-ray quiet quasar or else a nuclear starburst with an upper mass
limit greater than or equal to 60 M circle dot.