COORDINATION-COMPOUNDS OF 2-HYDROXY-4,6-D IPHENYL-THIOBENZOPHENONE - CHELATE COMPLEXES OF COBALT AND NICKEL, X-RAY STRUCTURE OF THE NICKEL COMPOUND

Authors
LORENZ B ZIMMERMANN T HUBENER R ABRAM U
Citation
B. Lorenz et al., COORDINATION-COMPOUNDS OF 2-HYDROXY-4,6-D IPHENYL-THIOBENZOPHENONE - CHELATE COMPLEXES OF COBALT AND NICKEL, X-RAY STRUCTURE OF THE NICKEL COMPOUND, Zeitschrift fur anorganische und allgemeine Chemie, 619(11), 1993, pp. 1905-1908
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
619
Issue
11
Year of publication
1993
Pages
1905 - 1908
Database
ISI
SICI code
0044-2313(1993)619:11<1905:CO2I-C>2.0.ZU;2-V
Abstract
2-Hydroxy-4,6-diphenyl-thiobenzophenone (HL) reacts under deprotonatio n with metal salts to chelate complexes. The reactions with nickel ace tate or cobalt acetate yield neutral complexes of the composition NiL2 and CoL3, respectively. The nickel compound crystallizes monoclinic i n the space group P2(1)/c (No. 14), a = 17.55(6), b = 26.69(4), c = 8. 49(9) angstrom, beta = 102.7(2)-degrees, Z = 4. The nickel atom has a distorted square-planar coordination sphere. The ligands are cis coord inated.