U. Calov et al., ACETAMIDINIUMHEXAFLUOROMETALLATES OF ALUM INUM, GALLIUM, INDIUM, VANADIUM, CHROMIUM, MANGANESE, IRON AND COBALT, Zeitschrift fur anorganische und allgemeine Chemie, 619(11), 1993, pp. 1939-1944
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The title compounds were crystallized from HF-containing aqueous solut
ions of their hexafluorometallate acids by adding acetamidine. Their u
nit cells were determined and the thermal decomposition was investigat
ed thermoanalytically. The crystal structure of [CH3C(NH2)2]3AlF6 was
determined: Space group P4(1)2(1)2/P4(3)2(1)2, a = 8,987(1), c = 17,89
4(3) angstrom, R 0,054. The unit cell parameters: [CH3C(NH2)2]3GaF6: a
= 9,078(1), c = 18,104(2) angstrom; [CH3C(NH2)2]3InF6: a = 9,277(1),
c = 18,545(2) angstrom; [CH3C(NH2)2]3VF6: a = 9,1201(6), c = 18,2197(6
) angstrom; [CH3C(NH2)2]3CrF6: a = 9,089(1), c = 18,132(2) angstrom; [
CH3C(NH2)2]3MnF6: a = 9,109(2), c = 18,241(3) angstrom; [CH3C(NH2)2]3F
eF6: a = 9,122(2), c = 18,189(6) angstrom; [CH3C(NH2)2]3CoF6: a = 9,08
4(1), c = 18,130(4) angstrom.