SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES

Authors
MCGHEE WD SELLA A OHARE D CLOKE FGN MEHNERT C GREEN MLH
Citation
Wd. Mcghee et al., SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES, Journal of organometallic chemistry, 459(1-2), 1993, pp. 125-130
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
459
Issue
1-2
Year of publication
1993
Pages
125 - 130
Database
ISI
SICI code
0022-328X(1993)459:1-2<125:SASOT1>2.0.ZU;2-4
Abstract
The synthesis of vanadium and molybdenum complexes derived from nitrog en-containing heterocyclic aromatic ligands are described. The first e ta-pyrazine sandwich complex, [V(eta6-Me4pyrazine)2], has been prepare d by metal vapour synthesis and crystallographically characterized. Th e synthesis of (Mo(eta6-2,6-lutidine)2] has been substantially improve d, and provides a convenient starting material for the preparation of the new half-sandwich compounds [Mo(eta6-2,6-lutidine)(PMe3)3] and [Mo (eta6-2,6-lutidine)(eta3-allyl)Cl]2.