M. Jaime et al., HALL-EFFECT SIGN ANOMALY AND SMALL-POLARON CONDUCTION IN (LA1-XGDX)(0.67)CA0.33MNO3, Physical review letters, 78(5), 1997, pp. 951-954
The Hall coefficient of Gd-doped La2/3Ca1/3MnO3 exhibits Arrhenius beh
avior over a temperature range from 2T(c) to 4T(c), with an activation
energy very close to 2/3 that of the electrical conductivity. Althoug
h both the doping level and thermoelectric coefficient indicate holeli
ke conduction, the Hall coefficient is electronlike. This unusual resu
lt provides strong evidence in favor of small-polaronic conduction in
the paramagnetic regime of the manganites.