Photoluminescence studies of molecular beam epitaxy grown ZnSe-on-GaAs
layers are presented. The high sensitivity of the PL technique allowe
d for identification unintentional dopants in pure ZnSe sample. Charac
teristic photoluminescence lines due to extended defects were observed
. The experimental results obtained show a correlation between intenti
onal doping level and extended defects concentration. We conclude also
that even though molecular beam epitaxy layers are grown at low tempe
rature, the self-compensation mechanism may still be important. For he
avily doped sample edge emission is deactivated likely due to efficien
t energy transfer link with deep donor-acceptor pair bands.