Self-consistent linear muffin-tin orbital method is used to calculate
the band structure of ZnS/ZnSe (001) strained-layer superlattice and i
nvestigate the influence of hydrostatic pressure on the valence band o
ffset (VBO). Three different strain modes corresponding to various val
ues of the relative thicknesses of both materials are considered. A I
--> II type conversion associated with the conduction-band crossover b
etween the ZnSe well and ZnS barrier layers is found in agreement with
recent experimental data.