ELECTROREDUCTION OF 3-BROMOPYRENE IN DMF - A NEW ORGANIC ELECTROCHEMICAL OSCILLATOR

Authors
JAWORSKI JS LESZCZYNSKI P PAWLOWSKI S
Citation
Js. Jaworski et al., ELECTROREDUCTION OF 3-BROMOPYRENE IN DMF - A NEW ORGANIC ELECTROCHEMICAL OSCILLATOR, Collection of Czechoslovak Chemical Communications, 61(12), 1996, pp. 1715-1721
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
61
Issue
12
Year of publication
1996
Pages
1715 - 1721
Database
ISI
SICI code
0010-0765(1996)61:12<1715:EO3ID->2.0.ZU;2-2
Abstract
The reduction of 3-bromopyrene in DMF at a mercury electrode for scan rates lower than 0.1 V s(-1) is accompanied by a slow adsorption of an intermediate, resulting in a catalytic behaviour. The current oscilla tions take place in a region of the negative faradaic impedance.