EFFECT OF THE TRANSMISSION-REFLECTION PROPERTIES OF THE BARRIER FOR THE ACTIVATED COMPLEX ON THE RATE OF CHARGE-TRANSFER IN GASEOUS ION-MOLECULE REACTIONS

Authors
TURULSKI J MAZUREK A NIEDZIELSKI J
Citation
J. Turulski et al., EFFECT OF THE TRANSMISSION-REFLECTION PROPERTIES OF THE BARRIER FOR THE ACTIVATED COMPLEX ON THE RATE OF CHARGE-TRANSFER IN GASEOUS ION-MOLECULE REACTIONS, International journal of mass spectrometry and ion processes, 128(3), 1993, pp. 165-171
Citations number
17
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
International journal of mass spectrometry and ion processes → ACNP
ISSN journal
01681176
Volume
128
Issue
3
Year of publication
1993
Pages
165 - 171
Database
ISI
SICI code
0168-1176(1993)128:3<165:EOTTPO>2.0.ZU;2-Z
Abstract
A simple theory was used to investigate the effects of transmission-re flection properties of the barrier for the activated complex on the ch arge transfer rate. Contrary to some charge transfer models that dispe nse with the occurrence of an activated complex altogether, many of th e reactions examined do involve the formation of an activated complex characterized by a small barrier while some feature a barrier that is fairly large. The complete absence of any barrier also occurs but not as a rule.