NEW CYCLODISILAZANE MONOMERS

Authors
DUGUET E SCHAPPACHER M SOUM A
Citation
E. Duguet et al., NEW CYCLODISILAZANE MONOMERS, Journal of organometallic chemistry, 458(1-2), 1993, pp. 9-12
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
458
Issue
1-2
Year of publication
1993
Pages
9 - 12
Database
ISI
SICI code
0022-328X(1993)458:1-2<9:NCM>2.0.ZU;2-A
Abstract
N,N'-Dimethylcyclodisilazanes -SiMeR-NMe-SiMeR'-NMe- (R = R' = Me, Vi, or Et and R = Me, R' = Vi, Et, or Ph where Vi = vinyl) have been prep ared in good yield by cyclization of bis(methylamino)silanes with chlo rosilanes. H-1, C-13, Si-29 and N-15 NMR spectra have been assigned. T he four-membered cyclic structure of the compounds have been confirmed by mass spectrometry and IR absorption measurements.