1,3-DIOXA-[3]FERROCENOPHANES

Authors
HERBERHOLD M BRENDEL HD
Citation
M. Herberhold et Hd. Brendel, 1,3-DIOXA-[3]FERROCENOPHANES, Journal of organometallic chemistry, 458(1-2), 1993, pp. 205-209
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
458
Issue
1-2
Year of publication
1993
Pages
205 - 209
Database
ISI
SICI code
0022-328X(1993)458:1-2<205:1>2.0.ZU;2-C
Abstract
The reaction of 1,1'-ferrocenediol, Fe(C5H4OH)2, with dihalides (E'Cl2 ) in the presence of triethylamine has been used to synthesize the 1,3 -dioxa-[3]ferrocenophanes, Fe(C3H4O)2E' (E' = P(t)Bu, As(t)Bu, Sb(t)Bu , BPh). Starting from triphosgene, (Cl3CO)2CO, as a precursor of phosg ene (COCl2), the analogous 1,3-dichalcogena-[3]ferrocenophan-2-ones Fe (C5H4O)2CO and Fe(C5H4S)2CO were obtained. All new compounds were char acterized by their H-1 and 13 C NMR spectra as well as their mass spec tra.