PHOTOCHEMISTRY OF METHANESULPHINATOPENTACARBONYLMANGANESE, MN(CO)5(SO2CH3), IN FROZEN GAS MATRICES AT CA 12-K

Authors
REN X REST AJ
Citation
X. Ren et Aj. Rest, PHOTOCHEMISTRY OF METHANESULPHINATOPENTACARBONYLMANGANESE, MN(CO)5(SO2CH3), IN FROZEN GAS MATRICES AT CA 12-K, Journal of organometallic chemistry, 458(1-2), 1993, pp. 30000005-30000007
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
458
Issue
1-2
Year of publication
1993
Pages
30000005 - 30000007
Database
ISI
SICI code
0022-328X(1993)458:1-2<30000005:POMM>2.0.ZU;2-O
Abstract
Infrared spectroscopic evidence is presented which shows that photolys is of the S-sulphinato complex, Mn(CO)5(S-SO2CH3), in argon, methane, dinitrogen and carbon monoxide matrices at ca. 12 K produces first the O-sulphinato complex, Mn(CO)5(O-SO2CH3), which on further photolysis is converted into the O,O'-sulphinato complex, Mn(CO)4(O,O'-SO2CH3) wi th ejection of a CO ligand. Annealing the matrices to ca. 35 K results in reversal of the O,O'-sulphinato complex to the parent S-sulphinato complex.