SYNTHESIS AND STRUCTURE OF THE NICKEL A-FRAME COMPLEX NI2(MU-CNC6H5)(DPPM)2CL2

Authors
HINZE S GONG JK FANWICK PE KUBIAK CP
Citation
S. Hinze et al., SYNTHESIS AND STRUCTURE OF THE NICKEL A-FRAME COMPLEX NI2(MU-CNC6H5)(DPPM)2CL2, Journal of organometallic chemistry, 458(1-2), 1993, pp. 30000010-30000011
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
458
Issue
1-2
Year of publication
1993
Pages
30000010 - 30000011
Database
ISI
SICI code
0022-328X(1993)458:1-2<30000010:SASOTN>2.0.ZU;2-T
Abstract
Oxidative addition of phenyl isocyanide dichloride (C6H5NCCl2) to Ni(C OD)2 (COD = cycloocta-1,5-diene) in the presence of dppm (dppm = bis(d iphenylphosphino)methane) in toluene is found to be a high yield proce dure for the preparation of the new phenyl isocyanide-bridged A-frame complex, Ni2(mu-CNC6H5)(dppm)2Cl2. The title complex crystallizes in t he chiral space group P4(3)2(1)2 (a = 14.871(3), c = 25.790(7) angstro m, V = 5703.7 angstrom3, Z = 4) and its structure was determined by X- ray diffraction.