SYNTHESIS OF POLY(N-TERT-BUTYLAZIRIDINE)S WITH FUNCTIONAL END-GROUPS

Authors
CHRISTOVA DC VELICHKOVA RS PANAYOTOV IM
Citation
Dc. Christova et al., SYNTHESIS OF POLY(N-TERT-BUTYLAZIRIDINE)S WITH FUNCTIONAL END-GROUPS, Die Makromolekulare Chemie, 194(11), 1993, pp. 2975-2983
Citations number
9
Categorie Soggetti
Polymer Sciences
Journal title
Die Makromolekulare Chemie → ACNP
ISSN journal
0025116X
Volume
194
Issue
11
Year of publication
1993
Pages
2975 - 2983
Database
ISI
SICI code
0025-116X(1993)194:11<2975:SOPWFE>2.0.ZU;2-T
Abstract
Poly(N-tert-butylaziridine) (poly(TBA)) with hydroxy, amino, HO-C(O)-C H=CH-C(O)-and -P(O)(OCH3)2 end-groups were synthesized via termination reactions of living poly(TBA) with appropriate nucleophiles. 2-Aminoe thanol, sodium 2-aminoethylate, maleic anhydride and dimethyl phosphon ate were used. The functionally terminated oligomers were of uniform s ize and with a functionality near one.