We investigated the interface roughness of InP/As quantum wells using
photoluminescence and secondary ion mass spectroscopy. Typical photolu
minescence spectra consist of multiple lines. The energies of the obse
rved peaks have a remarkable behavior; namely, both the peak energies
and the separations between peaks change from sample to sample. We dis
cuss the interpretation of the observed emission lines in connection w
ith questions such as interface roughness, island formation and latera
l confinement. We also discuss the strong influence of parameters such
as the growth temperature and the substrate orientation on the interf
ace roughness.