Nc. Verma et Vt. Srinivasan, A COMPUTER-INTERFACE FOR DATA-ACQUISITION FROM A PULSED NUCLEAR-MAGNETIC-RESONANCE SPECTROMETER, Analytical instrumentation, 21(3-4), 1993, pp. 99-112
A interface is described for rapid data acquisition from a pulsed nucl
ear magnetic resonance (NMR) spectrometer. The system is built using a
n IBM compatible PC/XT and a commercial data acquisition card. The com
puterization has been accomplished without making any changes in the c
ommercial spectrometer. The data acquisition program is written in Bas
ic using the driver routines supplied along with the data acquisition
cal T1 evaluation consists of measuring the FID signal intensities for
various values of tau ranging from 10 msec to about 2.5 times the exp
ected T1 value. Measurements of T1 can also be carried out by using th
e inversion recovery pulse sequence 180-degrees x-tau-90-degrees y6. T
ransverse relaxation time (T2) is measured using the Carr-Purcell-Meib
oom-Gill7,8 pulse sequence ees)y-2tau-(180-degrees)y-2tau-(180-degrees
)y..... The intensities of the spin echoes following each 180-degrees
pulse are measured by A/D converter. The trigger for the A/D converter
is provided by the spectrometer at the peak of each spin echo. The si
gnal intensities for both T1 and T2 measurements are averaged over a n
umber of times to improve the signal to noise ratio.