Thermodynamic measurements of equilibrium oxygen partial pressure (P(O
2)) as a function of oxygen content at 1173K have been performed on La
1.84Sr0.16CuOy. These measurements confirmed the presence of traces of
an impurity phase of the type La8-xSrxCu8O20 (an oxygen-deficient, pe
rovskite structure) which is always present in sintered La2-xSrxCuOy t
ype oxides. Samples of La1.84Sr0.16CuOy with controlled oxygen content
were prepared taking into account the amount of oxygen related to thi
s impurity phase. The superconducting properties of these samples were
studied through ac susceptibility and a correlation where T(c) decrea
ses as the oxygen content decreases was found.