THERMAL-CRACKING MECHANISM OF A MIXTURE OF METHYLCYCLOPENTADIENE DIMERS

Authors
LAUER JC LAURENS T SCHMITQUILES F NICOLE D MATLENGIEWICZ M HENZEL N
Citation
Jc. Lauer et al., THERMAL-CRACKING MECHANISM OF A MIXTURE OF METHYLCYCLOPENTADIENE DIMERS, Analusis, 21(8), 1993, pp. 359-365
Citations number
18
Categorie Soggetti
Chemistry Analytical
Journal title
Analusis → ACNP
ISSN journal
03654877
Volume
21
Issue
8
Year of publication
1993
Pages
359 - 365
Database
ISI
SICI code
0365-4877(1993)21:8<359:TMOAMO>2.0.ZU;2-Q
Abstract
The diMe-DCPD and Me-DCPD isomers of very low concentration contained in a commercial mixture were determined based on the C-13 NMR and GC-M S results and by employing correlations between Kovats' and Branching indices. This identification allowed us to propose some statistical ru les to determine the potential content of the monomers in different mi xtures by comparing with experimental results obtained by thermal crac king.