COMPLEX-FORMATION OF IRIDIUM(IV) DURING SORPTION BY NITROGEN-CONTAINING ADSORBENTS BASED ON POLYACRYLONITRILE

Authors
SIMANOVA SA ZAMOROVA IN KAZAKEVICH YE KONOVALOV LV BELYAEV AN ERSHOVA OA
Citation
Sa. Simanova et al., COMPLEX-FORMATION OF IRIDIUM(IV) DURING SORPTION BY NITROGEN-CONTAINING ADSORBENTS BASED ON POLYACRYLONITRILE, Journal of applied chemistry of the USSR, 65(10), 1992, pp. 1875-1881
Citations number
17
Categorie Soggetti
Chemistry Applied
Journal title
Journal of applied chemistry of the USSR → ACNP
ISSN journal
0021888X
Volume
65
Issue
10
Year of publication
1992
Part
2
Pages
1875 - 1881
Database
ISI
SICI code
0021-888X(1992)65:10<1875:COIDSB>2.0.ZU;2-X
Abstract
The sorption properties of fibrous adsorbents of the Tiopan type - cop olymers of polyacrylonitrile with grafted polyglycidyl methacrylate, c ontaining diethyldithiocarbamate, thiol, and 8-mercaptoquinoline group s - with respect to K-2[IrCl6] were studied. The kinetic and capacity characteristics or the sorbents were determined in hydrochloric acid a nd chloride solutions. The mechanism of the complex formation of iridi um with fibers as polymer ligands was established.