STRUCTURE AND CONVERSIONS OF RADICALS OF THE HYDRATED FORM OF GLYCOLIC ALDEHYDE IN INDIRECT RADIOLYSIS OF ITS AQUEOUS-SOLUTIONS

Authors
GLUSHONOK GK KOSOBUTSKII VS MAIBORODA VD PETRYAEV EL
Citation
Gk. Glushonok et al., STRUCTURE AND CONVERSIONS OF RADICALS OF THE HYDRATED FORM OF GLYCOLIC ALDEHYDE IN INDIRECT RADIOLYSIS OF ITS AQUEOUS-SOLUTIONS, High energy chemistry, 27(2), 1993, pp. 95-99
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
High energy chemistry → ACNP
ISSN journal
00181439
Volume
27
Issue
2
Year of publication
1993
Pages
95 - 99
Database
ISI
SICI code
0018-1439(1993)27:2<95:SACORO>2.0.ZU;2-Z
Abstract
A quantum chemical calculation (MNDO) of the structure of the molecule and radicals of the hydrated form of glycolic aldehyde was performed. The structures of the radicals formed by cleavage of C-H bonds in the molecule at the C1 and C2 positions are compared. It was shown that t he radical at C1 is responsible for the formation of acetic acid - the end product of radiolysis of an aqueous solution of glycolic aldehyde .