We have developed radiation-sensitive charge-transfer-complex-based po
lymer materials which on irradiation form intermediate particles and c
ompounds that enable etching of bismuth and aluminum metals. Metallic
films, deposited on a substrate and coated with a radiation-sensitive
material, were subjected to etching. Under electron irradiation with D
= 0.8 and 640 Gy in a regime with and without optical enhancement of
the latent image the optical density of the Bi film decreased from 1.4
to 0.7. The maximum achieved sensitivity for an Al film corresponds t
o a decrease of optical density from 4 to 2 under irradiation with D a
pproximately 600 Gy.