F. Stoppa et L. Lupini, MINERALOGY AND PETROLOGY OF THE POLINO MONTICELLITE CALCIOCARBONATITE(CENTRAL ITALY), Mineralogy and petrology, 49(3-4), 1993, pp. 213-231
Two small diatremes, about 0.25 my old, cut through Liassic limestones
about 1 km NNE of the village of Polino (Long. 12 degrees 50'54''E-La
t. 42 degrees 35'34''N; Central Italy). The material filling the large
r diatreme is mainly composed of a tuffisite with abundant lapilli sho
wing concentric structure. Both unaltered country-rocks and massive hy
pabyssal carbonatite occur in the tuffisite as angular clasts and bloc
ks, from a few mm up to more than 1 m in diameter. The Polino rock occ
urs in a strongly-potassic igneous district (Umbria Latium Ultra-alkal
ine District) which comprises phonolitic pyroclastic rocks and very ra
re kamafugitic lavas. Massive carbonatite blocks have an average mode
of 53% Sr-Ba-rich calcite, 23% Fe-monticellite, 9% Th-perovskite plus
Ti-magnetite, 6% Cr-phlogopite, 6% forsteritic olivine, about 2% Zr-sc
horlomite and ca. 1% Si-CO-OH apatite. Perovskite, schorlomite, and ap
atite form cognate phases, whereas olivine and phlogopite, often repla
ced by monticellite, occur as nodules and as discrete grains with comp
ositions and deformation features typical of mantle xenocrysts found i
n alkali basalts and ultramafic rocks. High modal content of Ca-carbon
ate, high Sr, Ba and LREE contents of calcite, the presence of rare mi
nerals peculiar to carbonatitic rocks and an essential amount of monti
cellite indicate classification of the Polino rock as a monticellite c
alciocarbonatite. The Polino rock represents a carbonatitic melt stron
gly contaminated by mantle-crystal debris. It displays unusual geochem
ical features having trace elements closer to those of the regional-as
sociated kamafugitic rocks rather than to those of common carbonatites
.