DENSE ENERGETIC COMPOUNDS OF C, H, N, AND O-ATOMS .3. AZOLYL]-5H-[1,2,3]TRIAZOLO[4,5-C][1,2,5]OXADIAZOLE

Citation
A. Gunasekaran et Jh. Boyer, DENSE ENERGETIC COMPOUNDS OF C, H, N, AND O-ATOMS .3. AZOLYL]-5H-[1,2,3]TRIAZOLO[4,5-C][1,2,5]OXADIAZOLE, Heteroatom chemistry, 4(5), 1993, pp. 521-524
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10427163
Volume
4
Issue
5
Year of publication
1993
Pages
521 - 524
Database
ISI
SICI code
1042-7163(1993)4:5<521:DECOCH>2.0.ZU;2-J
Abstract
Diazidoazofurazan 8 was obtained from the bis-diazonium salt of diamin oazofurazan 7 by treatment with sodium azide and underwent thermolysis to zido-(1,2,5)oxadiazolyl]-5H-[1,2,3]triazolo[4,5-c] [1,2,5] oxadiaz ole 5. The corresponding amine 13 was obtained from the azide 5 by red uction with stannous chloride and was oxidized by ammonium persulfate to itro-(1,2,5)oxadiazolyl]-5H-[1,2,3]triazolo[4,5-c] [1,2,5]oxadiazol e 1. The azide 5 was converted to a phosphinimine 9 in a reaction with triphenylphosphine.