SYNTHESIS AND CRYSTAL-STRUCTURE OF A DINUCLEAR YTTRIUM(III)-(LANTHANIDE(III)-) COPPER(II) COMPLEX WITH AN UNUSUAL ,4,6-TRIS(TRIFLUOROMETHYL)-1,3-DIOXANE-4,6-DIOLATO LIGAND

Authors
WANG SN PANG Z SMITH KDL
Citation
Sn. Wang et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A DINUCLEAR YTTRIUM(III)-(LANTHANIDE(III)-) COPPER(II) COMPLEX WITH AN UNUSUAL ,4,6-TRIS(TRIFLUOROMETHYL)-1,3-DIOXANE-4,6-DIOLATO LIGAND, Inorganic chemistry, 32(23), 1993, pp. 4992-4993
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
23
Year of publication
1993
Pages
4992 - 4993
Database
ISI
SICI code
0020-1669(1993)32:23<4992:SACOAD>2.0.ZU;2-C
Abstract
A dinuclear Ln(III)-Cu(II) complex with an unusual ,4,6-tris(trifluoro methyl)-1,3-dioxane-4,6-diolato ligand has been synthesized and charac terized structurally. The 1,3-dioxane-4,6-diolato ligand is the produc t of cycloaddition of 1,1,1-trifluoro-2,2-propanediol to a hexafluoroa cetylacetonato ligand promoted by the metal complex.