HIGHLY REDUCED ORGANOMETALLICS .34. SYNTHESIS AND CHARACTERIZATION OF[R3SNTI(CO)6]-, A NEW CLASS OF TITANIUM CARBONYLS - MOLECULAR-STRUCTURE OF (C6H11)3SNTI(CO)6]-

Authors
ELLIS JE YUEN P
Citation
Je. Ellis et P. Yuen, HIGHLY REDUCED ORGANOMETALLICS .34. SYNTHESIS AND CHARACTERIZATION OF[R3SNTI(CO)6]-, A NEW CLASS OF TITANIUM CARBONYLS - MOLECULAR-STRUCTURE OF (C6H11)3SNTI(CO)6]-, Inorganic chemistry, 32(23), 1993, pp. 4998-4999
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
23
Year of publication
1993
Pages
4998 - 4999
Database
ISI
SICI code
0020-1669(1993)32:23<4998:HRO.SA>2.0.ZU;2-K
Abstract
The first examples of titanium carbonyls of the general formula LTi(CO )6 have been prepared by the reactions of [Ti(CO)6]2- with R3SnCl (R = Me, Ph, cyclohexyl). NMR spectra established that the products, [R3Sn Ti(CO)6]-, are fluxional in solution at room temperature. A single-cry stal X-ray study of [(C6H11)3SnTi(CO)6]- confirms the presence of seve n-coordinate titanium in this complex.