SYNTHESIS OF PERHALOALKANESULFONYL HALIDES AND THEIR SULFONIMIDE DERIVATIVES

Authors
HU LQ DESMARTEAU DD
Citation
Lq. Hu et Dd. Desmarteau, SYNTHESIS OF PERHALOALKANESULFONYL HALIDES AND THEIR SULFONIMIDE DERIVATIVES, Inorganic chemistry, 32(23), 1993, pp. 5007-5010
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
23
Year of publication
1993
Pages
5007 - 5010
Database
ISI
SICI code
0020-1669(1993)32:23<5007:SOPHAT>2.0.ZU;2-W
Abstract
Several perhalogenated alkanesulfonyl halides, RfSO2X (R(f) = CF3CF2, CF3CF2CF2, ClCF2CFClCF2CF2, CF3CCl2, CFCl2; X = Cl, F) and 1,6-bis(hal osulfonyl)perfluorohexanes, XO2S(CF2)6SO2X (X = Cl, F), have been prep ared via the sodium sulfinates obtained from dehalogenosulfination rea ctions of the respective alkyl halides. Selected sulfonyl fluorides we re further converted to the amides RxSO2NH2 and imides (RxSO2)2NH.