SYNTHESIS OF THE 1-ME2S-CENTER-DOT-B11H13 AND 2-ME2S-CENTER-DOT-B11H13 ISOMERS - CRYSTAL-STRUCTURES OF 2-ME2S-CENTER-DOT-B11H13 AND 7-ME2S-CENTER-DOT-B11H13

Authors
KELLER DL KESTER JG HUFFMAN JC TODD LJ
Citation
Dl. Keller et al., SYNTHESIS OF THE 1-ME2S-CENTER-DOT-B11H13 AND 2-ME2S-CENTER-DOT-B11H13 ISOMERS - CRYSTAL-STRUCTURES OF 2-ME2S-CENTER-DOT-B11H13 AND 7-ME2S-CENTER-DOT-B11H13, Inorganic chemistry, 32(23), 1993, pp. 5067-5070
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
23
Year of publication
1993
Pages
5067 - 5070
Database
ISI
SICI code
0020-1669(1993)32:23<5067:SOT1A2>2.0.ZU;2-S
Abstract
Treatment of Me3NH[B11H14] with excess H2SO4 and Me2S formed 7-Me2S.B1 1H13 (1) in good yield. Thermal rearrangement of 1 at 110-degrees-C in a sublimation apparatus formed a mixture of 1-Me2S.B11H13(2) and 2-Me 2S.B11H13 (3). Compound 1 was characterized by a single-crystal X-ray diffraction determination (space group P2(1)/c, a = 7.194(1) angstrom, b = 12.240(3) angstrom, c = 13.520(3) angstrom, beta = 102.60(1)degre es, Z = 4). Compound 3 was also characterized by a single-crystal X-ra y diffraction determination (space group P2(1)2(1)2(1), a = 8.936(1) a ngstrom, b = 10.280(1) angstrom, c = 12.629(1) angstrom, Z = 2).