A new open-chain monoterpene glycoside, anatolioside E (1), was isolat
ed from the leaves of Viburnum orientale in addition to three known ac
yclic monoterpene glycosides, betulalbusides A (2) and B (3), and l-2,
7-octadien-1,6-diol-6-O-beta-D-glucopyranoside (4). The structure of a
natolioside E (1) was elucidated on the basis of chemical and spectral
data as O-[beta-D-glucopyranosyl-(1''''''-->6''''')-2-(E), 6(R), >2''
'')-beta-D-glucopyranosyl-(1''''-->6''')-2(E), 6(R), ranosyl-(1''-->2'
)-beta-D-glucopyranosyl]linalool.