MG PBBR2 BIMETAL REDOX-PROMOTED STANNATION OF PROPARGYL, ALLYL, VINYL, AND ARYL HALIDES/

Authors
TANAKA H HAI AKMA OGAWA H TORII S
Citation
H. Tanaka et al., MG PBBR2 BIMETAL REDOX-PROMOTED STANNATION OF PROPARGYL, ALLYL, VINYL, AND ARYL HALIDES/, Synlett, (11), 1993, pp. 835-836
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1993
Pages
835 - 836
Database
ISI
SICI code
0936-5214(1993):11<835:MPBRSO>2.0.ZU;2-U
Abstract
Reductive coupling of propargylic bromides with tributylstannyl chlori de was performed in a regioselective manner by the aid of magnesium me tal and a catalytic amount of lead(II) bromide in THF, affording allen yltributylstannanes. In a similar manner, allyl-, vinyl-, and aryl-tri butylstannanes were prepared from the corresponding halides.