ALPHA-SULFINYL SUBSTITUTED RADICALS .2. STEREOSELECTIVE INTERMOLECULAR AND INTRAMOLECULAR ADDITION-REACTIONS OF ACYCLIC ALPHA-SULFINYL RADICALS

Authors
DEMESMAEKER A WALDNER A HOFFMANN P MINDT T
Citation
A. Demesmaeker et al., ALPHA-SULFINYL SUBSTITUTED RADICALS .2. STEREOSELECTIVE INTERMOLECULAR AND INTRAMOLECULAR ADDITION-REACTIONS OF ACYCLIC ALPHA-SULFINYL RADICALS, Synlett, (11), 1993, pp. 871-874
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
11
Year of publication
1993
Pages
871 - 874
Database
ISI
SICI code
0936-5214(1993):11<871:ASR.SI>2.0.ZU;2-0
Abstract
Acyclic alpha-sulfinyl radicals exhibit high diastereoselectivity in i ntermolecular as well as intramolecular addition reactions to C=C doub le bonds. Hydroxylic solvents such as alcohols cause either a loss of diastereoselectivity or have a minor effect as observed in the latter case.