Fl. Dickert et O. Schuster, MASS SENSITIVE DETECTION OF SOLVENT VAPORS WITH CALIX[N]ARENES - CONFORMATIONAL ADAPTATION TO THE ANALYTE, Advanced materials, 5(11), 1993, pp. 826-829
Calixarenes have a high molecular flexibility, facilitating an optimiz
ed adaptation to the shape of a large variety of guest molecules. Larg
e substituents result in conformationally rigid compounds (Figure) but
other calixarenes are ideal for coatings exhibiting high chemical sen
sitivity.