Ka. Gesheva et al., DEPOSITION AND STUDY OF CVD - TUNGSTEN AND MOLYBDENUM THIN-FILMS AND THEIR IMPACT ON MICROELECTRONICS TECHNOLOGY, Applied surface science, 73, 1993, pp. 86-89
Tungsten and molybdenum films have been deposited on silicon by the py
rolysis of hexacarbonyls at 400 degrees C under atmospheric pressure.
Auger analysis of W films produced by the pyrolysis of W(CO)(6) reveal
s a large amount of carbon and oxygen. Post-deposition rapid thermal a
nnealing at a temperature less than 800 degrees C and hydrogen-contain
ing atmosphere leads to obtaining low-resistivity thin-film materials,
based on refractory metals.