Si/CoSi2/Si heterostructures have been fabricated by sequentially depo
siting, in high vacuum, Co and Si onto (001)Si substrate. The growth o
f an epitaxial CoSi2 layer has been achieved by keeping the Si substra
te at 600 degrees C during Co deposition. The Si overlayer has been su
ccessively obtained by deposition under different experimental conditi
ons. Elevated substrate temperature has given rise to an epitaxial ove
rlayer, but the high adatom mobility has led to a non-uniform coverage
. A more uniform layer has been obtained by room-temperature depositio
n. The as-deposited amorphous layer has been subsequently crystallized
by thermal treatments preserving its uniformity, but the process resu
lted in a highly defective Si overlayer. Furthermore, a preliminary st
udy on the ion-beam-assisted deposition of Si onto CoSi2/Si heteroepit
axial structures has been performed.