CYANOMETHYL GROUP - A VERSATILE PROTECTIN G GROUP FOR PHENOLS, PRIMARY AND SECONDARY-AMINES, AND CARBAMATES

Authors
BENARAB A BOYE S SAVELON L GUILLAUMET G
Citation
A. Benarab et al., CYANOMETHYL GROUP - A VERSATILE PROTECTIN G GROUP FOR PHENOLS, PRIMARY AND SECONDARY-AMINES, AND CARBAMATES, Tetrahedron letters, 34(47), 1993, pp. 7567-7568
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
47
Year of publication
1993
Pages
7567 - 7568
Database
ISI
SICI code
0040-4039(1993)34:47<7567:CG-AVP>2.0.ZU;2-W
Abstract
The use of the cyanomethyl unit as a protecting group for phenols, pri mary and secondary amines, and carbamates is described. Optimized cond itions for formation and hydrolysis of cyanomethyl in the presence of the other hydrogenolysis-sensitive groups such as O- and N-benzyl grou ps are presented.