Jr. Gibbins et al., DETERMINATION OF RAPID HEATING VOLATILE MATTER CONTENTS AS A ROUTINE TEST, Combustion science and technology, 93(1-6), 1993, pp. 349-361
Better characterisation of coal volatile yields under rapid heating co
nditions could improve fuel matching for existing plant, leading to im
proved overall performance, and also assist in the development of adva
nced clean combustion technologies. The relative merits of entrained f
low and captive sample techniques for routine coal characterisation un
der rapid heating are discussed. Although the former can apply conditi
ons more representative of PF combustion, volatile yield measurements
are likely to be easier and more accurate in the latter. A version of
the well known wire-mesh captive sample reactor is described which dis
penses with fine thermocouples for temperature measurement and is ther
efore easier to use on a routine basis. Results obtained in this appar
atus for a variety of coals are presented. These show that the R facto
r, the ratio between yields under rapid heating conditions and the pro
ximate VM content, can vary significantly between coals. A brief compa
rison with results from drop tube reactors indicates approximately sim
ilar trends.