MECHANISM OF THE PLATINUM-PROMOTED CONVERSION OF CL2C=PR TO R-C-EQUIVALENT-TO-P, WHERE R=2,4,6-TRI-TERT-BUTYLPHENYL

Authors
JUN H ANGELICI RJ
Citation
H. Jun et Rj. Angelici, MECHANISM OF THE PLATINUM-PROMOTED CONVERSION OF CL2C=PR TO R-C-EQUIVALENT-TO-P, WHERE R=2,4,6-TRI-TERT-BUTYLPHENYL, Organometallics, 12(11), 1993, pp. 4265-4266
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
11
Year of publication
1993
Pages
4265 - 4266
Database
ISI
SICI code
0276-7333(1993)12:11<4265:MOTPCO>2.0.ZU;2-T
Abstract
The reaction of Cl2C=PR with Pt(PEt3)4 to give R-C=P and Pt(PEt3)2Cl2 proceeds through intermediates II and III. An X-ray diffraction study shows that the 2,4,6-tri-tert-butylphenyl ring in III is no longer aro matic. However, the aromaticity is restored when migration of the R gr oup from the P to C is completed in forming the R-C=P product.