THERMAL AND METAL-CATALYZED REARRANGEMENTS OF BIS(STANNYL)DIAZO DERIVATIVES INTO CARBODIIMIDES - CARBODIIMIDE-TRANSFER REACTIONS

Authors
VENEZIANI G REAU R BERTRAND G
Citation
G. Veneziani et al., THERMAL AND METAL-CATALYZED REARRANGEMENTS OF BIS(STANNYL)DIAZO DERIVATIVES INTO CARBODIIMIDES - CARBODIIMIDE-TRANSFER REACTIONS, Organometallics, 12(11), 1993, pp. 4289-4290
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
11
Year of publication
1993
Pages
4289 - 4290
Database
ISI
SICI code
0276-7333(1993)12:11<4289:TAMROB>2.0.ZU;2-8
Abstract
Thermolysis of bis(trimethylstannyl)diazomethane (1) or bis(tributylst annyl)diazomethane (2) affords the corresponding bis(stannyl)carbodiim ides 3-4. Bis(trimethylstannyl)carbodiimide (3) is also obtained at ro om temperature by palladium-catalyzed isomerization of diazo derivativ e 1 and is a powerful precursor of elaborated carbodiimides.