A CONVENIENT ENTRY TO SUBSTITUTED CATIONIC IRON-CARBENE COMPLEXES

Authors
NLATE S LAPINTE C GUERCHAIS V
Citation
S. Nlate et al., A CONVENIENT ENTRY TO SUBSTITUTED CATIONIC IRON-CARBENE COMPLEXES, Organometallics, 12(11), 1993, pp. 4657-4659
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
11
Year of publication
1993
Pages
4657 - 4659
Database
ISI
SICI code
0276-7333(1993)12:11<4657:ACETSC>2.0.ZU;2-N
Abstract
The alkoxycarbene complex [Fe(Cp)(CO)2-(=C(OMe)Me)][CF3SO3] (1) readi ly undergoes specific substitution of one or two carbonyl ligands, dep ending on the photochemical conditions. This method opens a route to v arious mono- and disubstituted methoxycarbene complexes which are othe rwise not accessible.