PALLADIUM-CATALYZED INSERTION OF NORBORNENES AND ETHYLENE INTO SILICON-TIN SIGMA-BONDS - SILYLSTANNATION OF ALKENES WITH SILYLSTANNANES

Authors
OBORA Y TSUJI Y ASAYAMA M KAWAMURA T
Citation
Y. Obora et al., PALLADIUM-CATALYZED INSERTION OF NORBORNENES AND ETHYLENE INTO SILICON-TIN SIGMA-BONDS - SILYLSTANNATION OF ALKENES WITH SILYLSTANNANES, Organometallics, 12(11), 1993, pp. 4697-4699
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
11
Year of publication
1993
Pages
4697 - 4699
Database
ISI
SICI code
0276-7333(1993)12:11<4697:PIONAE>2.0.ZU;2-Z
Abstract
Organosilylstannanes 1 react with norbornene (2a), benzonorbornadiene (2b), and ethylene (2c) at 130-degrees-C in the presence of a catalyti c amount of bis(dibenzylideneacetone)palladium combined with a trialky lphosphine to afford silylstannation products 3 in high yields.