The framework structures of two closely related molecular sieves, SSZ-
26 and SSZ-33, are described. These materials possess a previously mis
sing but desired structural feature in a group of industrially signifi
cant zeolites. They contain a three-dimensional pore system that provi
des access to the crystal interior through both 10- and 12-rings. This
property is a consequence of the organic structure-directing agents u
sed in the synthesis of these materials. These materials are examples
of the purposeful design of a micropore architecture. Both SSZ-26 and
SSZ-33 contain the 4=4-1 building unit that had been previously found
only in natural zeolites.