ACCELERATION OF THE CONJUGATE ADDITION OF TI ATE ENOLATES VIA LEWIS-ACID CATALYSIS

Authors
BERNARDI A CAVICCHIOLI M SCOLASTICO C
Citation
A. Bernardi et al., ACCELERATION OF THE CONJUGATE ADDITION OF TI ATE ENOLATES VIA LEWIS-ACID CATALYSIS, Tetrahedron, 49(47), 1993, pp. 10913-10916
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
49
Issue
47
Year of publication
1993
Pages
10913 - 10916
Database
ISI
SICI code
0040-4020(1993)49:47<10913:AOTCAO>2.0.ZU;2-6
Abstract
The conjugate addition of Ti ''ate'' complexes of ketone enolates to a alpha,beta-unsaturated ketones can be accelerated by activating the s ubstrate via complexation with t-BuMe2SiCl or trityl triflate.