FORMALIN AND PARAFORMALDEHYDE AS END-POINT INDICATORS IN CATALYTIC THERMOMETRIC TITRIMETRY

Citation
Oes. Godinho et al., FORMALIN AND PARAFORMALDEHYDE AS END-POINT INDICATORS IN CATALYTIC THERMOMETRIC TITRIMETRY, Analyst, 118(11), 1993, pp. 1453-1465
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032654
Volume
118
Issue
11
Year of publication
1993
Pages
1453 - 1465
Database
ISI
SICI code
0003-2654(1993)118:11<1453:FAPAEI>2.0.ZU;2-X
Abstract
The use of formalin solution as an end-point indicator in the titratio n of both acids and bases in aqueous solutions was investigated. In bo th instances, a lowering in temperature at the end-point, due to depol ymerization of poly(oxymethylene glycols), was observed. Endothermic e nd-points were also obtained by using paraformaldehyde as an end-point indicator in titrations of acids in aqueous solutions. The use of par aformaldehyde in the titration of very weak acids and of some sparingl y soluble acids solubilized in micellar suspensions of cationic deterg ents was also investigated.